A novel nanostructured spinel ZnCo2O4 electrode material: morphology conserved transformation from a hexagonal shaped nanodisk precursor and application in lithium ion batteries†

نویسندگان

  • Yongcai Qiu
  • Shihe Yang
  • Hong Deng
  • Limin Jin
  • Weishan Li
چکیده

In this paper, we report a successful synthesis of porous ZnCo2O4 nanoflakes by a morphologyconserved and pyrolysis-induced transformation of novel hexagonally shaped, highly ordered, and inorganic–organic–inorganic layered hybrid nanodisks. It is shown that the hexagonal hybrid nanodisks are constructed from organic molecule (ethylene glycol)-directed assembly of inorganic bilayers. The assembly mechanism has been established by a number of structural and spectroscopic techniques. The porous ZnCo2O4 nanoflakes have also been tested as a lithium ion battery electrode, showing high capacity and high cyclability.

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تاریخ انتشار 2010